MPSC PYQ

Sublimation

Sublimation is a Geography concept from the MPSC syllabus, tested in 3 past MPSC questions (2017). Below are those real questions with their correct answers and explanations, plus the concepts worth being comfortable with first.

Real questions
3
Years tested
1 · 2017–2017
In context
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What you need to know first

States of matterAtmospheric moistureSeparation techniquesSublimation definitionBasic chemistry terms

Real questions that test this

वाफेचे रूपांतर बर्फात होण्याच्या क्रियेस ________ म्हणतात. The process of conversion of water vapour into ice is known as

1)संप्लवन / Sublimation✓ Correct
2)अभिसरण / Condensation
3)बाष्पीभवन / Evaporation
4)बाष्पोत्सर्जन / Evapotranspiration

Sublimation is the direct transition of a substance from solid to gas or vice versa (such as water vapour directly into ice or frost, or solid to vapour).

Read the following passage and answer the questions from 31 to 35: During the interactions with a group of standard VI students, Dr. Sarvesh demonstrated various experiments involving physical changes viz. Vapourisation/Evaporation (liquid to gas), Melting (solid to liquid), Sublimation (solid to gas) and Chemical changes viz. Neutralization (reaction between acid and alkali), Precipitation (reaction between ammonium chloride/potassium chloride and silver nitrate). This group enjoyed the session and demanded little more information regarding detection of cations and anions in the given solution. With this demand, Dr. Sarvesh designed three experiments (one by observing the changes in the colours of the test papers and another, just observing the change) to detect the presence of ammonium radical in the given salts. Dr. Sarvesh dissolved a small amount (approximately 0.100 g) of each, solid ammonium chloride and solid potassium chloride separately in 2.0 cm of de-ionised water, in two different test tubes labeled '1' and '2' respectively. Two drops of each of the above solutions were separately taken in three different dry test tubes forming two different sets; one set kept on the extreme left and another on the extreme right. The three test tubes, in each of the two sets, were gently heated on adding six drops of 2 N sodium hydroxide (alkali) to each and the evolved gases were carefully brought in contact, separately, with a moist red litmus paper, a moist turmeric paper and a glass rod dipped in dilute hydrochloric acid. Above the test tubes on the left hand side, in the first case, the paper turned blue (this was exactly opposite to acidic gases which turn moist blue litmus red), in the second case the paper turned brown and in the last case dense white fumes of ammonium chloride were observed. No such changes were observed in the colours of both the papers nor dense white fumes above the test tube on the right. Dr. Sarvesh explained that during the reactions between the reagents gaseous ammonia is liberated which is alkaline in nature and inferred that the solution in the left hand side test tubes contains ammonium radical while that in the right hand side test tube does not. Dr. Sarvesh then asked students to perform the test. In the first experiment, Ms. Riya, in addition to the earlier observations, found red litmus turning blue for the test tube on the right while Mr. Ravi, did not get the desired colour change of the turmeric paper on the left hand side test tube. Dr. Sarvesh explained to the students the proper way to perform the tests. Following the instructions from Dr. Sarvesh, when the students correctly performed the tests, they got the desired results.

वरील उताऱ्यावरून खालील निष्कर्ष काढता येतो : The following conclusion can be drawn from the above passage :

a)अमोनियम क्लोराईड पाण्यात फक्त विरघळते / Ammonium chloride is only soluble in water
b)अमोनियम क्लोराईड पाण्यात विरघळते, तसेच ते कदाचित संप्लवनशील आहे / Ammonium chloride is soluble in water as well as could be sublimative✓ Correct
c)अमोनियम क्लोराईड हे फक्त संप्लवनशील आहे / Ammonium chloride is only sublimative
d)अमोनियम क्लोराईड पाण्यात विरघळते, पण संप्लवनशील नाही / Ammonium chloride is soluble in water but not sublimative

Ammonium chloride dissolves in water and is also a well-known substance that undergoes sublimation upon heating, changing directly from solid to gas.

Read the following passage and answer the questions from 31 to 35: During the interactions with a group of standard VI students, Dr. Sarvesh demonstrated various experiments involving physical changes viz. Vapourisation/Evaporation (liquid to gas), Melting (solid to liquid), Sublimation (solid to gas) and Chemical changes viz. Neutralization (reaction between acid and alkali), Precipitation (reaction between ammonium chloride/potassium chloride and silver nitrate). This group enjoyed the session and demanded little more information regarding detection of cations and anions in the given solution. With this demand, Dr. Sarvesh designed three experiments (one by observing the changes in the colours of the test papers and another, just observing the change) to detect the presence of ammonium radical in the given salts. Dr. Sarvesh dissolved a small amount (approximately 0.100 g) of each, solid ammonium chloride and solid potassium chloride separately in 2.0 cm of de-ionised water, in two different test tubes labeled '1' and '2' respectively. Two drops of each of the above solutions were separately taken in three different dry test tubes forming two different sets; one set kept on the extreme left and another on the extreme right. The three test tubes, in each of the two sets, were gently heated on adding six drops of 2 N sodium hydroxide (alkali) to each and the evolved gases were carefully brought in contact, separately, with a moist red litmus paper, a moist turmeric paper and a glass rod dipped in dilute hydrochloric acid. Above the test tubes on the left hand side, in the first case, the paper turned blue (this was exactly opposite to acidic gases which turn moist blue litmus red), in the second case the paper turned brown and in the last case dense white fumes of ammonium chloride were observed. No such changes were observed in the colours of both the papers nor dense white fumes above the test tube on the right. Dr. Sarvesh explained that during the reactions between the reagents gaseous ammonia is liberated which is alkaline in nature and inferred that the solution in the left hand side test tubes contains ammonium radical while that in the right hand side test tube does not. Dr. Sarvesh then asked students to perform the test. In the first experiment, Ms. Riya, in addition to the earlier observations, found red litmus turning blue for the test tube on the right while Mr. Ravi, did not get the desired colour change of the turmeric paper on the left hand side test tube. Dr. Sarvesh explained to the students the proper way to perform the tests. Following the instructions from Dr. Sarvesh, when the students correctly performed the tests, they got the desired results.

दाट सफेद वाफा तयार झाल्या, कारण / Observations about white dense fumes are seen

(a)रासायनिक अभिक्रियेमुळे / as a result of a chemical change

(b)उदासीनीकरण अभिक्रियेमुळे / as a result of neutralization reaction

(c)अमोनियम क्लोराइड संप्लवनशील आहे म्हणून / because ammonium chloride sublimes

1)फक्त अ आणि ब / Only a and b✓ Correct
2)फक्त ब आणि क / Only b and c
3)फक्त अ आणि क / Only a and c
4)अ, ब आणि क / a, b and c

Dense white fumes are produced due to chemical reactions and specific property changes like the sublimation of ammonium chloride when heated/reacted.

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